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Journal Articles

Determination of optimal vapor pressure data by the second and third law methods

Nakajima, Kunihisa

Mass Spectrometry (Internet), 5(2), p.S0055_1 - S0055_6, 2016/12

https://doi.org/10.5702/massspectrometry.S0055

Though equilibrium vapor pressures are utilized to determine thermodynamic properties of not only gaseous species but also condensed phases, the obtained data often disagree by a factor of 100 and more. A new data analysis method is proposed using the so-called second and third law procedures to improve accuracy of vapor pressure measurements. It was found from examination of vapor pressures of cesium metaborate and silver that the analysis of the difference between the second and third law values can result in determination of an optimal data set. Since the new thermodynamic method does not require special techniques and or experiences in dealing with measured data, it is reliable and versatile to improve the accuracy of vapor pressure evaluation.

Journal Articles

Construction of a newly designed small-size mass spectrometer for helium isotope analysis; Toward the continuous monitoring of $$^{3}$$He/$$^{4}$$He ratios in natural fluids

Bajo, Kenichi*; Sumino, Hirochika*; Toyoda, Michisato*; Okazaki, Ryuji*; Osawa, Takahito; Ishihara, Morio*; Katakuse, Itsuo*; Notsu, Kenji*; Igarashi, Joji*; Nagao, Keisuke*

Mass Spectrometry (Internet), 1(2), p.A0009_1 - A0009_10, 2012/11

https://doi.org/10.5702/massspectrometry.A0009

The construction of a small-size, magnetic sector, single focusing mass spectrometer (He-MS) for the continuous, on-site monitoring of the He isotope ratio ($$^{3}$$He/$$^{4}$$He) is described. The instrument is capable of measuring $$^{4}$$He/$$^{20}$$Ne ratios dissolved in several different types of natural fluids of geochemical interest, such as groundwater and gas from hot springs, volcanoes and gas well fields. Ion optics of the He-MS was designed by using the ion trajectory simulation program TRIO so as to measure $$^{3}$$He and $$^{4}$$He simultaneously with a double collector system under mass resolution power of $$>$$ 500. Presently attained specifications of the He-MS are; (1) mass resolving power of ca. 490, enough to separate $$^{3}$$He$$^{+}$$ from interfering ions, HD$$^{+}$$ and H$$_{3}$$$$^{+}$$, (2) ultra-high vacuum condition, and (3) high sensitivity enough to detect $$^{3}$$He amount 3000000 atoms).

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